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History
(Greek lanthanein: to lie hidden) Mosander in 1839 extracted lanthana from impure cerium nitrate and recognized the new element. Lanthanum was isolated in relatively pure form in 1923. Iron exchange and solvent extraction techniques have led to much easier isolation of the so-called "rare-earth" elements.
Sources
Lanthanum is found in rare-earth minerals such as cerite, monazite, allanite, and bastnasite. Monazite and bastnasite are principal ores in which lanthanum occurs in percentages up to 25 percent and 38 percent respectively. Misch metal, used in making lighter flints, contains about 25 percent lanthanum. The availability of lanthanum and other rare earths has improved greatly in recent years. The metal can be produced by reducing the anhydrous fluoride with calcium .
Properties
Lanthanum is silvery white, malleable, ductile, and soft enough to be cut with a knife. It is one of the most reactive of the rare-earth metals. It oxidizes rapidly when exposed to air. Cold water attacks lanthanum slowly, while hot water attacks it much more rapidly. The metal reacts directly with elemental carbon, nitrogen, boron, selenium, silicon, phosphorus, sulfur, and with halogens. At 310єC, lanthanum changes from a hexagonal to a face-centered cubic structure, and at 865єC it again transforms into a body-centered cubic structure. A Periodic Table of the Elements at Los Alamos National Laboratory |